Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te...N chalcogen bonding

В журнале Chemical Communications, Vol. 56, Iss. 7, 1113-1116, 2020  (IF 6,29) опубликована статья с участием сотрудника Института:   А.В. Зибарева

Bis(2,1,3-benzotelluradiazolidyl)2,1,3-benzotelluradiazole: a pair of radical anions coupled by Te...N chalcogen bonding

Abstract

Reduction of 2,1,3-benzotelluradiazole (3) yielded a crystalline solid that features a trimeric dianion formally composed of two [3]˙− and one 3 bridged by unusually asymmetric Te⋯N chalcogen bonds. The solid is diamagnetic due to strong antiferromagnetic coupling, as revealed by CASSCF/CASPT2 and BS-DFT.

Альметрики: 

Метрики PlumX теперь доступны в Scopus: узнайте, как другие ученые используют ваши исследования