N.N. Vorozhtsov Novosibirsk Institute of Organic Chemistry
Of Siberian Branch of Russian Academy of Sciences

Образовательный курс для студентов и аспирантов

Marque S

Section 1: Fundamental radical chemistry

- L1: historical, stabilization vs stability (thermodynamic vs kinetics), nucleophilic,

electrophilic and ambiphilic radicals,

- L2: energetic: Pauling’s relationship and its variants, Bell-Evans-Polanyi-Semenov


- L3 + L4: Main reactions: H-transfer, addition, substitution, coupling, fragmentation,

Karash and Barton-Mccombie reactions

Section 2: basic in kinetics needed for radical polymerization

- L5: fundamentals in kinetics: first order, second order, competitive and successive

reactions, Ostwald principle, equilibrium

- L6: Arrhénius and Eyring relationships, and their limits. Curtin Hammett principle,

Hammond postulate and TS, energetics

- L7: LFER, Hammett constants, steric constants, few examples of applications.

Section 3: the link between fundamental radical reactions and radical polymerization

- L8: from radical addition to conventional radical polymerization

- L9: from Persistent radical Effect to Nitroxide Mediated Polymerization and Atom

Transfer Radical Polymerization (ATRP)

- L10 + L11 + L12: Nitroxide Mediated Polymerization and its variants

- L13 + L14: from Karash reaction to ATRP and its variants

- L15 + L16: from Barton-McCombie reaction to Reversible-Addition radical

Fragmentation Transfer polymerization

Section 4: Some examples of Applications of radical chemistry in Materials Sciences.

- L17: some applications of NMP, ATRP, and RAFT in Material Sciences

- L18: degradation of multi-layer films using a combination of techniques (EPR, IR,

ATRF, Raman, titration, Principal component Analysis, XPS).


Предварительное расписание

с 5 по 12 декабря

(ежедневно, кроме сб, вс)

12.00-13.30, 14.30-17.30


Д.А. Морозов, КОрХ НГУ, +7 913 928 43 35

Р.А. Бредихин, НИОХ СО РАН, +7 913 925 96 92